A very large Rh-Rh bond shortening on excitation of the [Rh 2(1,8-diisocyano-p-menthane)4]2+ ion by time-resolved synchrotron X-ray diffraction

Philip Coppens; Oksana Gerlits; Ivan I. Vorontsov; Andrey Yu Kovalevsky; Yu Sheng Chen; Tim Graber; Milan Gembicky; Irina V. Novozhilova

doi:10.1039/b409463h

A very large Rh-Rh bond shortening on excitation of the [Rh ₂(1,8-diisocyano-p-menthane)₄]²⁺ ion by time-resolved synchrotron X-ray diffraction

Philip Coppens
, Oksana Gerlits
, Ivan I. Vorontsov
, Andrey Yu Kovalevsky
, Yu Sheng Chen
, Tim Graber
, Milan Gembicky
, Irina V. Novozhilova

Research output: Contribution to journal › Article › peer-review

74 Scopus citations

Abstract

A very large Rh-Rh contraction of ∼0.85 Å occurs on excitation of the [Rh₂(1,8-diisocyano-p-menthane)₄]²⁺ ion to its triplet state.

Original language	English
Pages (from-to)	2144-2145
Number of pages	2
Journal	Chemical Communications
Issue number	19
DOIs	https://doi.org/10.1039/b409463h
State	Published - Nov 7 2004
Externally published	Yes

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@article{01647df7b79f4507ab47ca1299e027ba,

title = "A very large Rh-Rh bond shortening on excitation of the [Rh 2(1,8-diisocyano-p-menthane)4]2+ ion by time-resolved synchrotron X-ray diffraction",

abstract = "A very large Rh-Rh contraction of ∼0.85 {\AA} occurs on excitation of the [Rh2(1,8-diisocyano-p-menthane)4]2+ ion to its triplet state.",

author = "Philip Coppens and Oksana Gerlits and Vorontsov, \{Ivan I.\} and Kovalevsky, \{Andrey Yu\} and Chen, \{Yu Sheng\} and Tim Graber and Milan Gembicky and Novozhilova, \{Irina V.\}",

year = "2004",

month = nov,

day = "7",

doi = "10.1039/b409463h",

language = "English",

pages = "2144--2145",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "19",

}

TY - JOUR

T1 - A very large Rh-Rh bond shortening on excitation of the [Rh 2(1,8-diisocyano-p-menthane)4]2+ ion by time-resolved synchrotron X-ray diffraction

AU - Coppens, Philip

AU - Gerlits, Oksana

AU - Vorontsov, Ivan I.

AU - Kovalevsky, Andrey Yu

AU - Chen, Yu Sheng

AU - Graber, Tim

AU - Gembicky, Milan

AU - Novozhilova, Irina V.

PY - 2004/11/7

Y1 - 2004/11/7

N2 - A very large Rh-Rh contraction of ∼0.85 Å occurs on excitation of the [Rh2(1,8-diisocyano-p-menthane)4]2+ ion to its triplet state.

AB - A very large Rh-Rh contraction of ∼0.85 Å occurs on excitation of the [Rh2(1,8-diisocyano-p-menthane)4]2+ ion to its triplet state.

UR - https://www.scopus.com/pages/publications/8144230366

U2 - 10.1039/b409463h

DO - 10.1039/b409463h

M3 - Article

AN - SCOPUS:8144230366

SN - 1359-7345

SP - 2144

EP - 2145

JO - Chemical Communications

JF - Chemical Communications

IS - 19

ER -

A very large Rh-Rh bond shortening on excitation of the [Rh ₂(1,8-diisocyano-p-menthane)₄]²⁺ ion by time-resolved synchrotron X-ray diffraction

Abstract

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