A Tröger's base-derived microporous organic polymer: Design and applications in CO2/H2 capture and hydrogenation of CO2 to formic acid

Zhen Zhen Yang; Hongye Zhang; Bo Yu; Yanfei Zhao; Guipeng Ji; Zhimin Liu

doi:10.1039/c4cc08295h

A Tröger's base-derived microporous organic polymer: Design and applications in CO₂/H₂ capture and hydrogenation of CO₂ to formic acid

Zhen Zhen Yang, Hongye Zhang, Bo Yu, Yanfei Zhao, Guipeng Ji, Zhimin Liu

Research output: Contribution to journal › Article › peer-review

102 Scopus citations

Abstract

A Tröger's base-derived microporous organic polymer (TB-MOP) was designed, which could adsorb CO₂ and coordinate with a Ru(iii) complex. The resultant TB-MOP-Ru showed good CO₂ and H₂ adsorbing performances, and high efficiency for catalysing hydrogenation of CO₂ to HCOOH with a turnover number up to 2254 at 40 °C.

Original language	English
Pages (from-to)	1271-1274
Number of pages	4
Journal	Chemical Communications
Volume	51
Issue number	7
DOIs	https://doi.org/10.1039/c4cc08295h
State	Published - Jan 25 2015
Externally published	Yes

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10.1039/c4cc08295h

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abstract = "A Tr{\"o}ger's base-derived microporous organic polymer (TB-MOP) was designed, which could adsorb CO2 and coordinate with a Ru(iii) complex. The resultant TB-MOP-Ru showed good CO2 and H2 adsorbing performances, and high efficiency for catalysing hydrogenation of CO2 to HCOOH with a turnover number up to 2254 at 40 °C.",

author = "Yang, {Zhen Zhen} and Hongye Zhang and Bo Yu and Yanfei Zhao and Guipeng Ji and Zhimin Liu",

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AU - Yang, Zhen Zhen

AU - Zhang, Hongye

AU - Yu, Bo

AU - Zhao, Yanfei

AU - Ji, Guipeng

AU - Liu, Zhimin

PY - 2015/1/25

Y1 - 2015/1/25

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AB - A Tröger's base-derived microporous organic polymer (TB-MOP) was designed, which could adsorb CO2 and coordinate with a Ru(iii) complex. The resultant TB-MOP-Ru showed good CO2 and H2 adsorbing performances, and high efficiency for catalysing hydrogenation of CO2 to HCOOH with a turnover number up to 2254 at 40 °C.

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A Tröger's base-derived microporous organic polymer: Design and applications in CO₂/H₂ capture and hydrogenation of CO₂ to formic acid

Abstract

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