A topotactic synthetic methodology for highly fluorine-doped mesoporous metal oxides

Zhen An Qiao; Suree S. Brown; Jamie Adcock; Gabriel M. Veith; J. Chris Bauer; E. Andrew Payzant; Raymond R. Unocic; Sheng Dai

doi:10.1002/anie.201107812

A topotactic synthetic methodology for highly fluorine-doped mesoporous metal oxides

Zhen An Qiao, Suree S. Brown, Jamie Adcock, Gabriel M. Veith, J. Chris Bauer, E. Andrew Payzant, Raymond R. Unocic, Sheng Dai

Research output: Contribution to journal › Article › peer-review

18 Scopus citations

Abstract

F tactic: Highly fluorine-doped mesoporous metal oxides (up to 40 atom %) were synthesized by topotactic fluorination synthesis with mesoporous metal oxides as starting materials and fluorine as the fluorination agent. The surface areas, pore sizes, pore volumes, and F atomic concentrations of these materials could be adjusted over a wide range by varying the fluorination time and temperature.

Original language	English
Pages (from-to)	2888-2893
Number of pages	6
Journal	Angewandte Chemie - International Edition
Volume	51
Issue number	12
DOIs	https://doi.org/10.1002/anie.201107812
State	Published - Mar 19 2012

Keywords

doping
fluorine
mesoporous materials
synthetic methods

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10.1002/anie.201107812

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abstract = "F tactic: Highly fluorine-doped mesoporous metal oxides (up to 40 atom \%) were synthesized by topotactic fluorination synthesis with mesoporous metal oxides as starting materials and fluorine as the fluorination agent. The surface areas, pore sizes, pore volumes, and F atomic concentrations of these materials could be adjusted over a wide range by varying the fluorination time and temperature.",

keywords = "doping, fluorine, mesoporous materials, synthetic methods",

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T1 - A topotactic synthetic methodology for highly fluorine-doped mesoporous metal oxides

AU - Qiao, Zhen An

AU - Brown, Suree S.

AU - Adcock, Jamie

AU - Veith, Gabriel M.

AU - Bauer, J. Chris

AU - Payzant, E. Andrew

AU - Unocic, Raymond R.

AU - Dai, Sheng

PY - 2012/3/19

Y1 - 2012/3/19

N2 - F tactic: Highly fluorine-doped mesoporous metal oxides (up to 40 atom %) were synthesized by topotactic fluorination synthesis with mesoporous metal oxides as starting materials and fluorine as the fluorination agent. The surface areas, pore sizes, pore volumes, and F atomic concentrations of these materials could be adjusted over a wide range by varying the fluorination time and temperature.

AB - F tactic: Highly fluorine-doped mesoporous metal oxides (up to 40 atom %) were synthesized by topotactic fluorination synthesis with mesoporous metal oxides as starting materials and fluorine as the fluorination agent. The surface areas, pore sizes, pore volumes, and F atomic concentrations of these materials could be adjusted over a wide range by varying the fluorination time and temperature.

KW - doping

KW - fluorine

KW - mesoporous materials

KW - synthetic methods

UR - https://www.scopus.com/pages/publications/84858171453

U2 - 10.1002/anie.201107812

DO - 10.1002/anie.201107812

M3 - Article

AN - SCOPUS:84858171453

SN - 1433-7851

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JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 12

ER -

A topotactic synthetic methodology for highly fluorine-doped mesoporous metal oxides

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Keywords

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