A theoretical assessment of the O3/H2O interference problem in the detection of natural levels of OH via laser induced fluorescence

D. D. Davis, M. O. Rodgers, S. D. Fischer, W. S. Heaps

Research output: Contribution to journalArticlepeer-review

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Abstract

Theoretical calculations are presented which estimate the possible magnitude of the O3/H2O derived OH interference signal resulting from the use of the laser‐induced fluorescence technique in measuring natural levels of tropospheric OH. Critical to this new assessment has been the measurement of the nascent OH quantum state distribution resulting from the reaction O(¹D) + H2O → 2OH, and an assessment of the subsequent rotational relaxation of the OH species when formed in high k levels.

Original languageEnglish
Pages (from-to)73-76
Number of pages4
JournalGeophysical Research Letters
Volume8
Issue number1
DOIs
StatePublished - Jan 1981

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