A tetrameric neptunyl(v) cluster supported by a Schiff base ligand

Roy Copping; Victor Mougel; Christophe Den Auwer; Claude Berthon; Philippe Moisy; Marinella Mazzanti

doi:10.1039/c2dt31072d

A tetrameric neptunyl(v) cluster supported by a Schiff base ligand

Roy Copping, Victor Mougel, Christophe Den Auwer, Claude Berthon, Philippe Moisy, Marinella Mazzanti

Research output: Contribution to journal › Article › peer-review

31 Scopus citations

Abstract

The first tetrameric cation-cation neptunyl(v) cluster, [{NpO ₂(salen)} ₄(μ ₈-K) ₂][K(18C6)Py] ₂, has been synthesized in non-aqueous solution from the reaction of [(NpO ₂Py ₅)(KI ₂Py ₂)] _n with K ₂salen and its structure determined in the solid state and in solution where the complex retains its tetrameric form.

Original language	English
Pages (from-to)	10900-10902
Number of pages	3
Journal	Dalton Transactions
Volume	41
Issue number	36
DOIs	https://doi.org/10.1039/c2dt31072d
State	Published - Sep 28 2012
Externally published	Yes

Access to Document

10.1039/c2dt31072d

Cite this

@article{2e55fee9b030408187b410cb89da6d4b,

title = "A tetrameric neptunyl(v) cluster supported by a Schiff base ligand",

abstract = "The first tetrameric cation-cation neptunyl(v) cluster, [{NpO 2(salen)} 4(μ 8-K) 2][K(18C6)Py] 2, has been synthesized in non-aqueous solution from the reaction of [(NpO 2Py 5)(KI 2Py 2)] n with K 2salen and its structure determined in the solid state and in solution where the complex retains its tetrameric form.",

author = "Roy Copping and Victor Mougel and {Den Auwer}, Christophe and Claude Berthon and Philippe Moisy and Marinella Mazzanti",

year = "2012",

month = sep,

day = "28",

doi = "10.1039/c2dt31072d",

language = "English",

volume = "41",

pages = "10900--10902",

journal = "Dalton Transactions",

issn = "1477-9226",

publisher = "Royal Society of Chemistry",

number = "36",

}

TY - JOUR

T1 - A tetrameric neptunyl(v) cluster supported by a Schiff base ligand

AU - Copping, Roy

AU - Mougel, Victor

AU - Den Auwer, Christophe

AU - Berthon, Claude

AU - Moisy, Philippe

AU - Mazzanti, Marinella

PY - 2012/9/28

Y1 - 2012/9/28

N2 - The first tetrameric cation-cation neptunyl(v) cluster, [{NpO 2(salen)} 4(μ 8-K) 2][K(18C6)Py] 2, has been synthesized in non-aqueous solution from the reaction of [(NpO 2Py 5)(KI 2Py 2)] n with K 2salen and its structure determined in the solid state and in solution where the complex retains its tetrameric form.

AB - The first tetrameric cation-cation neptunyl(v) cluster, [{NpO 2(salen)} 4(μ 8-K) 2][K(18C6)Py] 2, has been synthesized in non-aqueous solution from the reaction of [(NpO 2Py 5)(KI 2Py 2)] n with K 2salen and its structure determined in the solid state and in solution where the complex retains its tetrameric form.

UR - http://www.scopus.com/inward/record.url?scp=84865675604&partnerID=8YFLogxK

U2 - 10.1039/c2dt31072d

DO - 10.1039/c2dt31072d

M3 - Article

AN - SCOPUS:84865675604

SN - 1477-9226

VL - 41

SP - 10900

EP - 10902

JO - Dalton Transactions

JF - Dalton Transactions

IS - 36

ER -

A tetrameric neptunyl(v) cluster supported by a Schiff base ligand

Abstract

Access to Document

Other files and links

Fingerprint

Cite this