A stable fluorinated and alkylated lithium malonatoborate salt for lithium ion battery application

Shun Wan; Xueguang Jiang; Bingkun Guo; Sheng Dai; John B. Goodenough; Xiao Guang Sun

doi:10.1039/c5cc01428j

A stable fluorinated and alkylated lithium malonatoborate salt for lithium ion battery application

Shun Wan
, Xueguang Jiang
, Bingkun Guo
, Sheng Dai
, John B. Goodenough
, Xiao Guang Sun

Nanomaterials Chemistry Group

Research output: Contribution to journal › Article › peer-review

28 Scopus citations

Abstract

A new fluorinated and alkylated lithium malonatoborate salt, lithium bis(2-methyl-2-fluoromalonato)borate (LiBMFMB), has been synthesized for lithium ion battery application. A 0.8 M LiBMFMB solution is obtained in a mixture of ethylene carbonate (EC) and ethyl methyl carbonate (EMC) (1:2 by wt). The new LiBMFMB based electrolyte exhibits good cycling stability and rate capability in LiNi_0.5Mn_1.5O₄ and graphite based half-cells.

Original language	English
Pages (from-to)	9817-9820
Number of pages	4
Journal	Chemical Communications
Volume	51
Issue number	48
DOIs	https://doi.org/10.1039/c5cc01428j
State	Published - Jun 18 2015

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title = "A stable fluorinated and alkylated lithium malonatoborate salt for lithium ion battery application",

abstract = "A new fluorinated and alkylated lithium malonatoborate salt, lithium bis(2-methyl-2-fluoromalonato)borate (LiBMFMB), has been synthesized for lithium ion battery application. A 0.8 M LiBMFMB solution is obtained in a mixture of ethylene carbonate (EC) and ethyl methyl carbonate (EMC) (1:2 by wt). The new LiBMFMB based electrolyte exhibits good cycling stability and rate capability in LiNi0.5Mn1.5O4 and graphite based half-cells.",

author = "Shun Wan and Xueguang Jiang and Bingkun Guo and Sheng Dai and Goodenough, \{John B.\} and Sun, \{Xiao Guang\}",

note = "Publisher Copyright: {\textcopyright} 2015 The Royal Society of Chemistry.",

year = "2015",

month = jun,

day = "18",

doi = "10.1039/c5cc01428j",

language = "English",

volume = "51",

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TY - JOUR

T1 - A stable fluorinated and alkylated lithium malonatoborate salt for lithium ion battery application

AU - Wan, Shun

AU - Jiang, Xueguang

AU - Guo, Bingkun

AU - Dai, Sheng

AU - Goodenough, John B.

AU - Sun, Xiao Guang

PY - 2015/6/18

Y1 - 2015/6/18

N2 - A new fluorinated and alkylated lithium malonatoborate salt, lithium bis(2-methyl-2-fluoromalonato)borate (LiBMFMB), has been synthesized for lithium ion battery application. A 0.8 M LiBMFMB solution is obtained in a mixture of ethylene carbonate (EC) and ethyl methyl carbonate (EMC) (1:2 by wt). The new LiBMFMB based electrolyte exhibits good cycling stability and rate capability in LiNi0.5Mn1.5O4 and graphite based half-cells.

AB - A new fluorinated and alkylated lithium malonatoborate salt, lithium bis(2-methyl-2-fluoromalonato)borate (LiBMFMB), has been synthesized for lithium ion battery application. A 0.8 M LiBMFMB solution is obtained in a mixture of ethylene carbonate (EC) and ethyl methyl carbonate (EMC) (1:2 by wt). The new LiBMFMB based electrolyte exhibits good cycling stability and rate capability in LiNi0.5Mn1.5O4 and graphite based half-cells.

UR - https://www.scopus.com/pages/publications/84930643649

U2 - 10.1039/c5cc01428j

DO - 10.1039/c5cc01428j

M3 - Article

AN - SCOPUS:84930643649

SN - 1359-7345

VL - 51

SP - 9817

EP - 9820

JO - Chemical Communications

JF - Chemical Communications

IS - 48

ER -

A stable fluorinated and alkylated lithium malonatoborate salt for lithium ion battery application

Abstract

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