A remarkable Cr(III) organometallic compound formed by an unprecedented rearrangement of a formamidinate anion

R. Clérac; F. A. Cotton; C. A. Murillo; X. Wang

doi:10.1039/b007813l

A remarkable Cr(III) organometallic compound formed by an unprecedented rearrangement of a formamidinate anion

R. Clérac, F. A. Cotton, C. A. Murillo, X. Wang

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Abstract

In addition to a quadruply bonded dichromium(II,III) compound of unusual structure, we have obtained a dinuclear, antiferromagnetically coupled, Cr^III complex [Cr₂(μ-OMe)₂(η³ -N,C,Ń-H₂DpyF)₂ Cl₂·MeOH, H₂DpyF = CH(NH-pyridyl)₂] containing a transformed formamidinate group in which the central carbon atom has changed from sp² to sp³ hybridization and Cr-C bonds have been formed; details of the crystal structure of the organometallic compound are given here.

Original language	English
Pages (from-to)	205-206
Number of pages	2
Journal	Chemical Communications
Issue number	2
DOIs	https://doi.org/10.1039/b007813l
State	Published - Jan 21 2001
Externally published	Yes

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title = "A remarkable Cr(III) organometallic compound formed by an unprecedented rearrangement of a formamidinate anion",

abstract = "In addition to a quadruply bonded dichromium(II,III) compound of unusual structure, we have obtained a dinuclear, antiferromagnetically coupled, CrIII complex [Cr2(μ-OMe)2(η3 -N,C,{\'N}-H2DpyF)2 Cl2·MeOH, H2DpyF = CH(NH-pyridyl)2] containing a transformed formamidinate group in which the central carbon atom has changed from sp2 to sp3 hybridization and Cr-C bonds have been formed; details of the crystal structure of the organometallic compound are given here.",

author = "R. Cl{\'e}rac and Cotton, {F. A.} and Murillo, {C. A.} and X. Wang",

year = "2001",

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doi = "10.1039/b007813l",

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T1 - A remarkable Cr(III) organometallic compound formed by an unprecedented rearrangement of a formamidinate anion

AU - Clérac, R.

AU - Cotton, F. A.

AU - Murillo, C. A.

AU - Wang, X.

PY - 2001/1/21

Y1 - 2001/1/21

N2 - In addition to a quadruply bonded dichromium(II,III) compound of unusual structure, we have obtained a dinuclear, antiferromagnetically coupled, CrIII complex [Cr2(μ-OMe)2(η3 -N,C,Ń-H2DpyF)2 Cl2·MeOH, H2DpyF = CH(NH-pyridyl)2] containing a transformed formamidinate group in which the central carbon atom has changed from sp2 to sp3 hybridization and Cr-C bonds have been formed; details of the crystal structure of the organometallic compound are given here.

AB - In addition to a quadruply bonded dichromium(II,III) compound of unusual structure, we have obtained a dinuclear, antiferromagnetically coupled, CrIII complex [Cr2(μ-OMe)2(η3 -N,C,Ń-H2DpyF)2 Cl2·MeOH, H2DpyF = CH(NH-pyridyl)2] containing a transformed formamidinate group in which the central carbon atom has changed from sp2 to sp3 hybridization and Cr-C bonds have been formed; details of the crystal structure of the organometallic compound are given here.

UR - http://www.scopus.com/inward/record.url?scp=0035924955&partnerID=8YFLogxK

U2 - 10.1039/b007813l

DO - 10.1039/b007813l

M3 - Article

AN - SCOPUS:0035924955

SN - 1359-7345

SP - 205

EP - 206

JO - Chemical Communications

JF - Chemical Communications

IS - 2

ER -

A remarkable Cr(III) organometallic compound formed by an unprecedented rearrangement of a formamidinate anion

Abstract

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