A pure bismuth a site polar perovskite synthesized at ambient pressure

Craig A. Bridges; Mathieu Allix; Matthew R. Suchomel; Xiaojun Kuang; Iasmi Sterianou; Derek C. Sinclair; Matthew J. Rosseinsky

doi:10.1002/anie.200703146

A pure bismuth a site polar perovskite synthesized at ambient pressure

Craig A. Bridges
, Mathieu Allix
, Matthew R. Suchomel
, Xiaojun Kuang
, Iasmi Sterianou
, Derek C. Sinclair
, Matthew J. Rosseinsky

Research output: Contribution to journal › Article › peer-review

40 Scopus citations

Abstract

(Graph Presented) Getting the lead out: The bonding preferences of three octahedral-site cations permit the accommodation of the small, low-symmetry Bi³⁺ cation on the twelve-coordinate A site of the perovskite structure, affording a lead-free ferroelectric material (see picture). The graph shows the temperature dependence of the relative permittivity (Ο, left axis) and the dielectric loss (Δ, right axis).

Original language	English
Pages (from-to)	8785-8789
Number of pages	5
Journal	Angewandte Chemie - International Edition
Volume	46
Issue number	46
DOIs	https://doi.org/10.1002/anie.200703146
State	Published - 2007
Externally published	Yes

Keywords

Bismuth
Ferroelectric materials
Neutron diffraction
Perovskite phases
Polarity

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10.1002/anie.200703146

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title = "A pure bismuth a site polar perovskite synthesized at ambient pressure",

abstract = "(Graph Presented) Getting the lead out: The bonding preferences of three octahedral-site cations permit the accommodation of the small, low-symmetry Bi3+ cation on the twelve-coordinate A site of the perovskite structure, affording a lead-free ferroelectric material (see picture). The graph shows the temperature dependence of the relative permittivity (Ο, left axis) and the dielectric loss (Δ, right axis).",

keywords = "Bismuth, Ferroelectric materials, Neutron diffraction, Perovskite phases, Polarity",

author = "Bridges, \{Craig A.\} and Mathieu Allix and Suchomel, \{Matthew R.\} and Xiaojun Kuang and Iasmi Sterianou and Sinclair, \{Derek C.\} and Rosseinsky, \{Matthew J.\}",

year = "2007",

doi = "10.1002/anie.200703146",

language = "English",

volume = "46",

pages = "8785--8789",

journal = "Angewandte Chemie - International Edition",

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publisher = "wiley",

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TY - JOUR

T1 - A pure bismuth a site polar perovskite synthesized at ambient pressure

AU - Bridges, Craig A.

AU - Allix, Mathieu

AU - Suchomel, Matthew R.

AU - Kuang, Xiaojun

AU - Sterianou, Iasmi

AU - Sinclair, Derek C.

AU - Rosseinsky, Matthew J.

PY - 2007

Y1 - 2007

N2 - (Graph Presented) Getting the lead out: The bonding preferences of three octahedral-site cations permit the accommodation of the small, low-symmetry Bi3+ cation on the twelve-coordinate A site of the perovskite structure, affording a lead-free ferroelectric material (see picture). The graph shows the temperature dependence of the relative permittivity (Ο, left axis) and the dielectric loss (Δ, right axis).

AB - (Graph Presented) Getting the lead out: The bonding preferences of three octahedral-site cations permit the accommodation of the small, low-symmetry Bi3+ cation on the twelve-coordinate A site of the perovskite structure, affording a lead-free ferroelectric material (see picture). The graph shows the temperature dependence of the relative permittivity (Ο, left axis) and the dielectric loss (Δ, right axis).

KW - Bismuth

KW - Ferroelectric materials

KW - Neutron diffraction

KW - Perovskite phases

KW - Polarity

UR - https://www.scopus.com/pages/publications/36749009006

U2 - 10.1002/anie.200703146

DO - 10.1002/anie.200703146

M3 - Article

AN - SCOPUS:36749009006

SN - 1433-7851

VL - 46

SP - 8785

EP - 8789

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 46

ER -

A pure bismuth a site polar perovskite synthesized at ambient pressure

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Keywords

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