TY - JOUR
T1 - A pure bismuth a site polar perovskite synthesized at ambient pressure
AU - Bridges, Craig A.
AU - Allix, Mathieu
AU - Suchomel, Matthew R.
AU - Kuang, Xiaojun
AU - Sterianou, Iasmi
AU - Sinclair, Derek C.
AU - Rosseinsky, Matthew J.
PY - 2007
Y1 - 2007
N2 - (Graph Presented) Getting the lead out: The bonding preferences of three octahedral-site cations permit the accommodation of the small, low-symmetry Bi3+ cation on the twelve-coordinate A site of the perovskite structure, affording a lead-free ferroelectric material (see picture). The graph shows the temperature dependence of the relative permittivity (Ο, left axis) and the dielectric loss (Δ, right axis).
AB - (Graph Presented) Getting the lead out: The bonding preferences of three octahedral-site cations permit the accommodation of the small, low-symmetry Bi3+ cation on the twelve-coordinate A site of the perovskite structure, affording a lead-free ferroelectric material (see picture). The graph shows the temperature dependence of the relative permittivity (Ο, left axis) and the dielectric loss (Δ, right axis).
KW - Bismuth
KW - Ferroelectric materials
KW - Neutron diffraction
KW - Perovskite phases
KW - Polarity
UR - https://www.scopus.com/pages/publications/36749009006
U2 - 10.1002/anie.200703146
DO - 10.1002/anie.200703146
M3 - Article
AN - SCOPUS:36749009006
SN - 1433-7851
VL - 46
SP - 8785
EP - 8789
JO - Angewandte Chemie - International Edition
JF - Angewandte Chemie - International Edition
IS - 46
ER -