A paramagnetic precursor for polymeric supramolecular assemblies based on multiply bonded dimetal units: μ-acetato-acetonitriletris-(μ-N,N′- diphenylformamidinato)-diruthenium tetrafluoroborate dichloromethane hemisolvate

Panagiotis Angaridis; F. Albert Cotton; Carlos A. Murillo; Xiao Ping Wang

doi:10.1107/S0108270104032408

A paramagnetic precursor for polymeric supramolecular assemblies based on multiply bonded dimetal units: μ-acetato-acetonitriletris-(μ-N,N′- diphenylformamidinato)-diruthenium tetrafluoroborate dichloromethane hemisolvate

Panagiotis Angaridis
, F. Albert Cotton
, Carlos A. Murillo
, Xiao Ping Wang

Research output: Contribution to journal › Article › peer-review

3 Scopus citations

Abstract

The title compound, [Ru₂(C₁₃H₁₁N ₂)₃(C₂H₃O₂)(C ₂H₃N)]BF₄-0.5CH₂Cl₂ or [Ru₂(μ-DPhF)₃(μ-O₂CMe)(MeCN)]BF ₄·0.5CH₂-Cl₂, where DPhF is N,N′-diphenylformamidinate, crystallized as dark-blue block-shaped crystals. In the unit cell, the diruthenium cation lies on a general position, and the BF₄^- anions reside on two independent special positions with crystallographic twofold symmetry. Disorder was observed for one of the phenyl groups in the formamidinate ligand, the axial acetonitrile molecule and the interstitial dichloromethane molecule. The compound, which exhibits a long Ru-Ru bond of 2.4131 (5) Å, is the first {Ru ₂}⁵⁺ formamidinate species that is both equatorially and axially functionalized so that it can be used as a precursor for polymeric paramagnetic supramolecular assemblies.

Original language	English
Pages (from-to)	m71-m73
Journal	Acta Crystallographica Section C: Crystal Structure Communications
Volume	61
Issue number	2
DOIs	https://doi.org/10.1107/S0108270104032408
State	Published - Feb 2005
Externally published	Yes

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Angaridis, P., Cotton, F. A., Murillo, C. A., & Wang, X. P. (2005). A paramagnetic precursor for polymeric supramolecular assemblies based on multiply bonded dimetal units: μ-acetato-acetonitriletris-(μ-N,N′- diphenylformamidinato)-diruthenium tetrafluoroborate dichloromethane hemisolvate. Acta Crystallographica Section C: Crystal Structure Communications, 61(2), m71-m73. https://doi.org/10.1107/S0108270104032408

Angaridis, Panagiotis ; Cotton, F. Albert ; Murillo, Carlos A. et al. / A paramagnetic precursor for polymeric supramolecular assemblies based on multiply bonded dimetal units : μ-acetato-acetonitriletris-(μ-N,N′- diphenylformamidinato)-diruthenium tetrafluoroborate dichloromethane hemisolvate. In: Acta Crystallographica Section C: Crystal Structure Communications. 2005 ; Vol. 61, No. 2. pp. m71-m73.

@article{0e094b7d51f64064a309ca4b98b624f5,

title = "A paramagnetic precursor for polymeric supramolecular assemblies based on multiply bonded dimetal units: μ-acetato-acetonitriletris-(μ-N,N′- diphenylformamidinato)-diruthenium tetrafluoroborate dichloromethane hemisolvate",

abstract = "The title compound, [Ru2(C13H11N 2)3(C2H3O2)(C 2H3N)]BF4-0.5CH2Cl2 or [Ru2(μ-DPhF)3(μ-O2CMe)(MeCN)]BF 4·0.5CH2-Cl2, where DPhF is N,N′-diphenylformamidinate, crystallized as dark-blue block-shaped crystals. In the unit cell, the diruthenium cation lies on a general position, and the BF4- anions reside on two independent special positions with crystallographic twofold symmetry. Disorder was observed for one of the phenyl groups in the formamidinate ligand, the axial acetonitrile molecule and the interstitial dichloromethane molecule. The compound, which exhibits a long Ru-Ru bond of 2.4131 (5) {\AA}, is the first \{Ru 2\}5+ formamidinate species that is both equatorially and axially functionalized so that it can be used as a precursor for polymeric paramagnetic supramolecular assemblies.",

author = "Panagiotis Angaridis and Cotton, \{F. Albert\} and Murillo, \{Carlos A.\} and Wang, \{Xiao Ping\}",

year = "2005",

month = feb,

doi = "10.1107/S0108270104032408",

language = "English",

volume = "61",

pages = "m71--m73",

journal = "Acta Crystallographica Section C: Crystal Structure Communications",

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Angaridis, P, Cotton, FA, Murillo, CA & Wang, XP 2005, 'A paramagnetic precursor for polymeric supramolecular assemblies based on multiply bonded dimetal units: μ-acetato-acetonitriletris-(μ-N,N′- diphenylformamidinato)-diruthenium tetrafluoroborate dichloromethane hemisolvate', Acta Crystallographica Section C: Crystal Structure Communications, vol. 61, no. 2, pp. m71-m73. https://doi.org/10.1107/S0108270104032408

A paramagnetic precursor for polymeric supramolecular assemblies based on multiply bonded dimetal units: μ-acetato-acetonitriletris-(μ-N,N′- diphenylformamidinato)-diruthenium tetrafluoroborate dichloromethane hemisolvate. / Angaridis, Panagiotis; Cotton, F. Albert; Murillo, Carlos A. et al.
In: Acta Crystallographica Section C: Crystal Structure Communications, Vol. 61, No. 2, 02.2005, p. m71-m73.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - A paramagnetic precursor for polymeric supramolecular assemblies based on multiply bonded dimetal units

T2 - μ-acetato-acetonitriletris-(μ-N,N′- diphenylformamidinato)-diruthenium tetrafluoroborate dichloromethane hemisolvate

AU - Angaridis, Panagiotis

AU - Cotton, F. Albert

AU - Murillo, Carlos A.

AU - Wang, Xiao Ping

PY - 2005/2

Y1 - 2005/2

N2 - The title compound, [Ru2(C13H11N 2)3(C2H3O2)(C 2H3N)]BF4-0.5CH2Cl2 or [Ru2(μ-DPhF)3(μ-O2CMe)(MeCN)]BF 4·0.5CH2-Cl2, where DPhF is N,N′-diphenylformamidinate, crystallized as dark-blue block-shaped crystals. In the unit cell, the diruthenium cation lies on a general position, and the BF4- anions reside on two independent special positions with crystallographic twofold symmetry. Disorder was observed for one of the phenyl groups in the formamidinate ligand, the axial acetonitrile molecule and the interstitial dichloromethane molecule. The compound, which exhibits a long Ru-Ru bond of 2.4131 (5) Å, is the first {Ru 2}5+ formamidinate species that is both equatorially and axially functionalized so that it can be used as a precursor for polymeric paramagnetic supramolecular assemblies.

AB - The title compound, [Ru2(C13H11N 2)3(C2H3O2)(C 2H3N)]BF4-0.5CH2Cl2 or [Ru2(μ-DPhF)3(μ-O2CMe)(MeCN)]BF 4·0.5CH2-Cl2, where DPhF is N,N′-diphenylformamidinate, crystallized as dark-blue block-shaped crystals. In the unit cell, the diruthenium cation lies on a general position, and the BF4- anions reside on two independent special positions with crystallographic twofold symmetry. Disorder was observed for one of the phenyl groups in the formamidinate ligand, the axial acetonitrile molecule and the interstitial dichloromethane molecule. The compound, which exhibits a long Ru-Ru bond of 2.4131 (5) Å, is the first {Ru 2}5+ formamidinate species that is both equatorially and axially functionalized so that it can be used as a precursor for polymeric paramagnetic supramolecular assemblies.

UR - https://www.scopus.com/pages/publications/30944434909

U2 - 10.1107/S0108270104032408

DO - 10.1107/S0108270104032408

M3 - Article

AN - SCOPUS:30944434909

SN - 0108-2701

VL - 61

SP - m71-m73

JO - Acta Crystallographica Section C: Crystal Structure Communications

JF - Acta Crystallographica Section C: Crystal Structure Communications

IS - 2

ER -

Angaridis P, Cotton FA, Murillo CA, Wang XP. A paramagnetic precursor for polymeric supramolecular assemblies based on multiply bonded dimetal units: μ-acetato-acetonitriletris-(μ-N,N′- diphenylformamidinato)-diruthenium tetrafluoroborate dichloromethane hemisolvate. Acta Crystallographica Section C: Crystal Structure Communications. 2005 Feb;61(2):m71-m73. doi: 10.1107/S0108270104032408

A paramagnetic precursor for polymeric supramolecular assemblies based on multiply bonded dimetal units: μ-acetato-acetonitriletris-(μ-N,N′- diphenylformamidinato)-diruthenium tetrafluoroborate dichloromethane hemisolvate

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