A novel helical double-layered cobalt(ll)-organic framework with tetranuclear [Co4(μ3-OH)2] clusters linked by an unsymmetrical pyridylbenzoate ligand

Junhua Luo; Yusheng Zhao; Hongwu Xu; Tiffany L. Kinnibrugh; Dali Yang; Tatiana V. Timofeeva; Luke L. Daemen; Jianzhong Zhang; Wei Bao; Joe D. Thompson; Robert P. Currier

doi:10.1021/ic701003z

A novel helical double-layered cobalt(ll)-organic framework with tetranuclear [Co₄(μ₃-OH)₂] clusters linked by an unsymmetrical pyridylbenzoate ligand

Junhua Luo, Yusheng Zhao, Hongwu Xu, Tiffany L. Kinnibrugh, Dali Yang, Tatiana V. Timofeeva, Luke L. Daemen, Jianzhong Zhang, Wei Bao, Joe D. Thompson, Robert P. Currier

Research output: Contribution to journal › Article › peer-review

90 Scopus citations

Abstract

A novel cobalt(ll)-organic framework, [Co₂(OH)(3,4-PBC) ₃]_n (I), has been acquired by the reaction of CoO with an unsymmetrical pyridylbenzoate ligand, 3-pyrid-4-ylbenzoic acid (3,4-PBC). Single-crystal X-ray diffraction studies reveal that it is comprised of [Co ^II₄(μ₃-OH)₂] clusters linked by the unsymmetrical ligand 3,4-PBC, forming a novel helical double-layered metal-organic architecture. A significant overall antiferromagnetic behavior has been observed for this compound.

Original language	English
Pages (from-to)	9021-9023
Number of pages	3
Journal	Inorganic Chemistry
Volume	46
Issue number	22
DOIs	https://doi.org/10.1021/ic701003z
State	Published - Oct 29 2007
Externally published	Yes

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Luo, J., Zhao, Y., Xu, H., Kinnibrugh, T. L., Yang, D., Timofeeva, T. V., Daemen, L. L., Zhang, J., Bao, W., Thompson, J. D., & Currier, R. P. (2007). A novel helical double-layered cobalt(ll)-organic framework with tetranuclear [Co₄(μ₃-OH)₂] clusters linked by an unsymmetrical pyridylbenzoate ligand. Inorganic Chemistry, 46(22), 9021-9023. https://doi.org/10.1021/ic701003z

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title = "A novel helical double-layered cobalt(ll)-organic framework with tetranuclear [Co4(μ3-OH)2] clusters linked by an unsymmetrical pyridylbenzoate ligand",

abstract = "A novel cobalt(ll)-organic framework, [Co2(OH)(3,4-PBC) 3]n (I), has been acquired by the reaction of CoO with an unsymmetrical pyridylbenzoate ligand, 3-pyrid-4-ylbenzoic acid (3,4-PBC). Single-crystal X-ray diffraction studies reveal that it is comprised of [Co II4(μ3-OH)2] clusters linked by the unsymmetrical ligand 3,4-PBC, forming a novel helical double-layered metal-organic architecture. A significant overall antiferromagnetic behavior has been observed for this compound.",

author = "Junhua Luo and Yusheng Zhao and Hongwu Xu and Kinnibrugh, {Tiffany L.} and Dali Yang and Timofeeva, {Tatiana V.} and Daemen, {Luke L.} and Jianzhong Zhang and Wei Bao and Thompson, {Joe D.} and Currier, {Robert P.}",

year = "2007",

month = oct,

day = "29",

doi = "10.1021/ic701003z",

language = "English",

volume = "46",

pages = "9021--9023",

journal = "Inorganic Chemistry",

issn = "0020-1669",

publisher = "American Chemical Society",

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T1 - A novel helical double-layered cobalt(ll)-organic framework with tetranuclear [Co4(μ3-OH)2] clusters linked by an unsymmetrical pyridylbenzoate ligand

AU - Luo, Junhua

AU - Zhao, Yusheng

AU - Xu, Hongwu

AU - Kinnibrugh, Tiffany L.

AU - Yang, Dali

AU - Timofeeva, Tatiana V.

AU - Daemen, Luke L.

AU - Zhang, Jianzhong

AU - Bao, Wei

AU - Thompson, Joe D.

AU - Currier, Robert P.

PY - 2007/10/29

Y1 - 2007/10/29

N2 - A novel cobalt(ll)-organic framework, [Co2(OH)(3,4-PBC) 3]n (I), has been acquired by the reaction of CoO with an unsymmetrical pyridylbenzoate ligand, 3-pyrid-4-ylbenzoic acid (3,4-PBC). Single-crystal X-ray diffraction studies reveal that it is comprised of [Co II4(μ3-OH)2] clusters linked by the unsymmetrical ligand 3,4-PBC, forming a novel helical double-layered metal-organic architecture. A significant overall antiferromagnetic behavior has been observed for this compound.

AB - A novel cobalt(ll)-organic framework, [Co2(OH)(3,4-PBC) 3]n (I), has been acquired by the reaction of CoO with an unsymmetrical pyridylbenzoate ligand, 3-pyrid-4-ylbenzoic acid (3,4-PBC). Single-crystal X-ray diffraction studies reveal that it is comprised of [Co II4(μ3-OH)2] clusters linked by the unsymmetrical ligand 3,4-PBC, forming a novel helical double-layered metal-organic architecture. A significant overall antiferromagnetic behavior has been observed for this compound.

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U2 - 10.1021/ic701003z

DO - 10.1021/ic701003z

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SN - 0020-1669

VL - 46

SP - 9021

EP - 9023

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 22

ER -

A novel helical double-layered cobalt(ll)-organic framework with tetranuclear [Co₄(μ₃-OH)₂] clusters linked by an unsymmetrical pyridylbenzoate ligand

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