TY - JOUR
T1 - A new stable organic metal based on the BEDO-TTF donor and the doubly charged nitroprusside anion, (BEDO-TTF)4[Fe(CN)5NO]
AU - Zorina, L. V.
AU - Khasanov, S. S.
AU - Shibaeva, R. P.
AU - Gener, M.
AU - Rousseau, R.
AU - Canadell, E.
AU - Kushch, L. A.
AU - Yagubskii, E. B.
AU - Drozdova, O. O.
AU - Yakushi, K.
PY - 2000
Y1 - 2000
N2 - (BEDO-TTF)4[Fe(CN)5NO] was synthesized by electrocrystallization using the nitroprussides M2[Fe(CN)5NO]·2H2O (M = K, Rb) as supporting electrolytes and TCE (1,1,2-trichloroethane) and DCE (1,2-dichloroethane) as solvents. The crystal structure of this new salt (a = 4.0251(3), b = 15.266(2), c = 19.259(2) Å, α = 97.02(1), β = 93.23(1), γ = 96.04(1)°, V = 1165.1(2) Å3, Z = 3/4, space group P1) is characterized by the presence of β'-type radical cation layers and anion layers containing disordered nitroprusside anions. The stoichiometry was confirmed by a micro-Raman spectroscopic study and the band structure and Fermi surface of this new salt were studied by means of the extended Huckel tight binding method. (BEDO-TTF)4[Fe(CN)5NO] is a two dimensional metal stable down to liquid helium temperatures.
AB - (BEDO-TTF)4[Fe(CN)5NO] was synthesized by electrocrystallization using the nitroprussides M2[Fe(CN)5NO]·2H2O (M = K, Rb) as supporting electrolytes and TCE (1,1,2-trichloroethane) and DCE (1,2-dichloroethane) as solvents. The crystal structure of this new salt (a = 4.0251(3), b = 15.266(2), c = 19.259(2) Å, α = 97.02(1), β = 93.23(1), γ = 96.04(1)°, V = 1165.1(2) Å3, Z = 3/4, space group P1) is characterized by the presence of β'-type radical cation layers and anion layers containing disordered nitroprusside anions. The stoichiometry was confirmed by a micro-Raman spectroscopic study and the band structure and Fermi surface of this new salt were studied by means of the extended Huckel tight binding method. (BEDO-TTF)4[Fe(CN)5NO] is a two dimensional metal stable down to liquid helium temperatures.
UR - http://www.scopus.com/inward/record.url?scp=0033817251&partnerID=8YFLogxK
U2 - 10.1039/b003433i
DO - 10.1039/b003433i
M3 - Article
AN - SCOPUS:0033817251
SN - 0959-9428
VL - 10
SP - 2017
EP - 2023
JO - Journal of Materials Chemistry
JF - Journal of Materials Chemistry
IS - 9
ER -