TY - JOUR
T1 - A neutron powder diffraction study of Fe and Ni distributions in synthetic pentlandite and violarite using 60Ni isotope
AU - Tenailleau, Christophe
AU - Etschmann, Barbara
AU - Ibberson, Richard M.
AU - Pring, Allan
PY - 2006
Y1 - 2006
N2 - Cation ordering in two important iron nickel sulfide minerals, pentlandite and violarite, was studied by neutron powder diffraction using samples prepared with isotopically enriched 60Ni. Pentlandite of composition Fe4.8Ni4.2 S8, annealed at 150° C for 1 month has a disordered Ni/Fe distribution with Ni occupying 57(2)% of the octahedral site and 46(1)% of the tetrahedral site with a unit cell repeat of 10.1075(1) Å. After annealing for a further 2 months at 150 °C the Ni/Fe distribution is still disordered with 53(2)% Ni in the octahedral site and 48(2)% Ni in the tetrahedral site and the cell parameter increased by 0.21% possibly due to slight readjustment of the Fe/Ni ratio. Synthetic violarite, FeNi2S4, prepared at 300 °C, exhibits ordering of Ni onto the tetrahedral site, with Fe and the remaining Ni sharing the octahedral site. In situ neutron diffraction heating experiments in which pentlandite and violarite were heated up to 300 °C for 12 hours did not alter the Ni/Fe distribution between tetrahedral and octahedral sites. Violarite did not exhibit any evidence of magnetic ordering upon cooling to -173 °C. The interatomic distances in the two structures indicate that in pentlandite Fe2+ and Ni2+ are high spin and in violarite Fe2+ is low spin with Ni3+ with an inverted spinel structural type.
AB - Cation ordering in two important iron nickel sulfide minerals, pentlandite and violarite, was studied by neutron powder diffraction using samples prepared with isotopically enriched 60Ni. Pentlandite of composition Fe4.8Ni4.2 S8, annealed at 150° C for 1 month has a disordered Ni/Fe distribution with Ni occupying 57(2)% of the octahedral site and 46(1)% of the tetrahedral site with a unit cell repeat of 10.1075(1) Å. After annealing for a further 2 months at 150 °C the Ni/Fe distribution is still disordered with 53(2)% Ni in the octahedral site and 48(2)% Ni in the tetrahedral site and the cell parameter increased by 0.21% possibly due to slight readjustment of the Fe/Ni ratio. Synthetic violarite, FeNi2S4, prepared at 300 °C, exhibits ordering of Ni onto the tetrahedral site, with Fe and the remaining Ni sharing the octahedral site. In situ neutron diffraction heating experiments in which pentlandite and violarite were heated up to 300 °C for 12 hours did not alter the Ni/Fe distribution between tetrahedral and octahedral sites. Violarite did not exhibit any evidence of magnetic ordering upon cooling to -173 °C. The interatomic distances in the two structures indicate that in pentlandite Fe2+ and Ni2+ are high spin and in violarite Fe2+ is low spin with Ni3+ with an inverted spinel structural type.
KW - Cation ordering
KW - Neutron diffraction
KW - Ni isotope
KW - Pentlandite
KW - Thiospinel
KW - Violarite
UR - http://www.scopus.com/inward/record.url?scp=33748541063&partnerID=8YFLogxK
U2 - 10.2138/am.2006.2144
DO - 10.2138/am.2006.2144
M3 - Article
AN - SCOPUS:33748541063
SN - 0003-004X
VL - 91
SP - 1442
EP - 1447
JO - American Mineralogist
JF - American Mineralogist
IS - 8-9
ER -