A mixed-valence compound with one unpaired electron delocalized over four molybdenum atoms in a cyclic tetranuclear ion

F. Albert LeCottoni; Chun Y. Liu; Carlos A. Murillo; Xiaoping Wang

doi:10.1039/b306822f

A mixed-valence compound with one unpaired electron delocalized over four molybdenum atoms in a cyclic tetranuclear ion

F. Albert LeCottoni, Chun Y. Liu, Carlos A. Murillo, Xiaoping Wang

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Abstract

The first oxidation of a species derived from a compound having two linked, quadruply-bonded Mo₂ units has been performed and [[cis-Mo₂(DAniF)₂]₂(¼-Cl)₄]PF₆, 2, has been isolated and characterized in many ways; it has one unpaired electron and a fully delocalized structure where the Mo-Mo distances increase from 2.1191(4) Å in the reduced species to 2.1453(3) Å in 2 and the K _c of 1.3 × 10⁹ is three orders of magnitude larger than that of the Creutz-Taube ion.

Original language	English
Pages (from-to)	2190-2191
Number of pages	2
Journal	Chemical Communications
Volume	3
Issue number	17
DOIs	https://doi.org/10.1039/b306822f
State	Published - 2003
Externally published	Yes

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title = "A mixed-valence compound with one unpaired electron delocalized over four molybdenum atoms in a cyclic tetranuclear ion",

abstract = "The first oxidation of a species derived from a compound having two linked, quadruply-bonded Mo2 units has been performed and [[cis-Mo2(DAniF)2]2(¼-Cl)4]PF6, 2, has been isolated and characterized in many ways; it has one unpaired electron and a fully delocalized structure where the Mo-Mo distances increase from 2.1191(4) {\AA} in the reduced species to 2.1453(3) {\AA} in 2 and the K c of 1.3 × 109 is three orders of magnitude larger than that of the Creutz-Taube ion.",

author = "LeCottoni, \{F. Albert\} and Liu, \{Chun Y.\} and Murillo, \{Carlos A.\} and Xiaoping Wang",

year = "2003",

doi = "10.1039/b306822f",

language = "English",

volume = "3",

pages = "2190--2191",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "17",

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TY - JOUR

T1 - A mixed-valence compound with one unpaired electron delocalized over four molybdenum atoms in a cyclic tetranuclear ion

AU - LeCottoni, F. Albert

AU - Liu, Chun Y.

AU - Murillo, Carlos A.

AU - Wang, Xiaoping

PY - 2003

Y1 - 2003

N2 - The first oxidation of a species derived from a compound having two linked, quadruply-bonded Mo2 units has been performed and [[cis-Mo2(DAniF)2]2(¼-Cl)4]PF6, 2, has been isolated and characterized in many ways; it has one unpaired electron and a fully delocalized structure where the Mo-Mo distances increase from 2.1191(4) Å in the reduced species to 2.1453(3) Å in 2 and the K c of 1.3 × 109 is three orders of magnitude larger than that of the Creutz-Taube ion.

AB - The first oxidation of a species derived from a compound having two linked, quadruply-bonded Mo2 units has been performed and [[cis-Mo2(DAniF)2]2(¼-Cl)4]PF6, 2, has been isolated and characterized in many ways; it has one unpaired electron and a fully delocalized structure where the Mo-Mo distances increase from 2.1191(4) Å in the reduced species to 2.1453(3) Å in 2 and the K c of 1.3 × 109 is three orders of magnitude larger than that of the Creutz-Taube ion.

UR - https://www.scopus.com/pages/publications/0043236586

U2 - 10.1039/b306822f

DO - 10.1039/b306822f

M3 - Article

AN - SCOPUS:0043236586

SN - 1359-7345

VL - 3

SP - 2190

EP - 2191

JO - Chemical Communications

JF - Chemical Communications

IS - 17

ER -

A mixed-valence compound with one unpaired electron delocalized over four molybdenum atoms in a cyclic tetranuclear ion

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