A metal-organic framework functionalized with free carboxylic acid sites and its selective binding of a Cl(H2O)4- cluster

Radu Custelcean; Maryna G. Gorbunova

doi:10.1021/ja055528o

A metal-organic framework functionalized with free carboxylic acid sites and its selective binding of a Cl(H₂O)₄^- cluster

Radu Custelcean, Maryna G. Gorbunova

Chemical Separations Group

Research output: Contribution to journal › Article › peer-review

202 Scopus citations

Abstract

A metal-organic framework with one-dimensional channels decorated with -COOH binding sites was synthesized under aqueous acidic conditions, which inhibited the participation of these groups to metal coordination or self-association by hydrogen bonding. This material selectively includes Cl(H₂O)₄^- clusters in its channels, as revealed by single-crystal X-ray diffraction analysis, which represents the first structural characterization of such a water-chloride cluster.

Original language	English
Pages (from-to)	16362-16363
Number of pages	2
Journal	Journal of the American Chemical Society
Volume	127
Issue number	47
DOIs	https://doi.org/10.1021/ja055528o
State	Published - Nov 30 2005

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title = "A metal-organic framework functionalized with free carboxylic acid sites and its selective binding of a Cl(H2O)4- cluster",

abstract = "A metal-organic framework with one-dimensional channels decorated with -COOH binding sites was synthesized under aqueous acidic conditions, which inhibited the participation of these groups to metal coordination or self-association by hydrogen bonding. This material selectively includes Cl(H2O)4- clusters in its channels, as revealed by single-crystal X-ray diffraction analysis, which represents the first structural characterization of such a water-chloride cluster.",

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N2 - A metal-organic framework with one-dimensional channels decorated with -COOH binding sites was synthesized under aqueous acidic conditions, which inhibited the participation of these groups to metal coordination or self-association by hydrogen bonding. This material selectively includes Cl(H2O)4- clusters in its channels, as revealed by single-crystal X-ray diffraction analysis, which represents the first structural characterization of such a water-chloride cluster.

AB - A metal-organic framework with one-dimensional channels decorated with -COOH binding sites was synthesized under aqueous acidic conditions, which inhibited the participation of these groups to metal coordination or self-association by hydrogen bonding. This material selectively includes Cl(H2O)4- clusters in its channels, as revealed by single-crystal X-ray diffraction analysis, which represents the first structural characterization of such a water-chloride cluster.

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A metal-organic framework functionalized with free carboxylic acid sites and its selective binding of a Cl(H₂O)₄^- cluster

Abstract

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