A large-surface-area boracite-network-topology porous MOF constructed from a conjugated ligand exhibiting a high hydrogen uptake capacity

Xi Sen Wang; Shengqian Ma; Daqiang Yuan; Ji Woong Yoon; Young Kyu Hwang; Jong San Chang; Xiaoping Wang; Mads Ry Jørgensen; Yu Sheng Chen; Hong Cai Zhou

doi:10.1021/ic901073w

A large-surface-area boracite-network-topology porous MOF constructed from a conjugated ligand exhibiting a high hydrogen uptake capacity

Xi Sen Wang
, Shengqian Ma
, Daqiang Yuan
, Ji Woong Yoon
, Young Kyu Hwang
, Jong San Chang
, Xiaoping Wang
, Mads Ry Jørgensen
, Yu Sheng Chen
, Hong Cai Zhou

Research output: Contribution to journal › Article › peer-review

67 Scopus citations

Abstract

A new porous metal - organic framework, PCN-20 with a twisted boracite net topology, was constructed based on a highly conjugated planar tricarboxylate ligand; PCN-20 possesses a large Langmuir surface area of over 4200 m ²/g as well as demonstrates a high hydrogen uptake capacity of 6.2 wt % at 77 K and 50 bar.

Original language	English
Pages (from-to)	7519-7521
Number of pages	3
Journal	Inorganic Chemistry
Volume	48
Issue number	16
DOIs	https://doi.org/10.1021/ic901073w
State	Published - Aug 17 2009
Externally published	Yes

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10.1021/ic901073w

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title = "A large-surface-area boracite-network-topology porous MOF constructed from a conjugated ligand exhibiting a high hydrogen uptake capacity",

abstract = "A new porous metal - organic framework, PCN-20 with a twisted boracite net topology, was constructed based on a highly conjugated planar tricarboxylate ligand; PCN-20 possesses a large Langmuir surface area of over 4200 m 2/g as well as demonstrates a high hydrogen uptake capacity of 6.2 wt \% at 77 K and 50 bar.",

author = "Wang, \{Xi Sen\} and Shengqian Ma and Daqiang Yuan and Yoon, \{Ji Woong\} and Hwang, \{Young Kyu\} and Chang, \{Jong San\} and Xiaoping Wang and J{\o}rgensen, \{Mads Ry\} and Chen, \{Yu Sheng\} and Zhou, \{Hong Cai\}",

year = "2009",

month = aug,

day = "17",

doi = "10.1021/ic901073w",

language = "English",

volume = "48",

pages = "7519--7521",

journal = "Inorganic Chemistry",

issn = "0020-1669",

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T1 - A large-surface-area boracite-network-topology porous MOF constructed from a conjugated ligand exhibiting a high hydrogen uptake capacity

AU - Wang, Xi Sen

AU - Ma, Shengqian

AU - Yuan, Daqiang

AU - Yoon, Ji Woong

AU - Hwang, Young Kyu

AU - Chang, Jong San

AU - Wang, Xiaoping

AU - Jørgensen, Mads Ry

AU - Chen, Yu Sheng

AU - Zhou, Hong Cai

PY - 2009/8/17

Y1 - 2009/8/17

N2 - A new porous metal - organic framework, PCN-20 with a twisted boracite net topology, was constructed based on a highly conjugated planar tricarboxylate ligand; PCN-20 possesses a large Langmuir surface area of over 4200 m 2/g as well as demonstrates a high hydrogen uptake capacity of 6.2 wt % at 77 K and 50 bar.

AB - A new porous metal - organic framework, PCN-20 with a twisted boracite net topology, was constructed based on a highly conjugated planar tricarboxylate ligand; PCN-20 possesses a large Langmuir surface area of over 4200 m 2/g as well as demonstrates a high hydrogen uptake capacity of 6.2 wt % at 77 K and 50 bar.

UR - https://www.scopus.com/pages/publications/68949158209

U2 - 10.1021/ic901073w

DO - 10.1021/ic901073w

M3 - Article

AN - SCOPUS:68949158209

SN - 0020-1669

VL - 48

SP - 7519

EP - 7521

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 16

ER -

A large-surface-area boracite-network-topology porous MOF constructed from a conjugated ligand exhibiting a high hydrogen uptake capacity

Abstract

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