A large-surface-area boracite-network-topology porous MOF constructed from a conjugated ligand exhibiting a high hydrogen uptake capacity

Xi Sen Wang; Shengqian Ma; Daqiang Yuan; Ji Woong Yoon; Young Kyu Hwang; Jong San Chang; Xiaoping Wang; Mads Ry Jørgensen; Yu Sheng Chen; Hong Cai Zhou

doi:10.1021/ic901073w

A large-surface-area boracite-network-topology porous MOF constructed from a conjugated ligand exhibiting a high hydrogen uptake capacity

Xi Sen Wang, Shengqian Ma, Daqiang Yuan, Ji Woong Yoon, Young Kyu Hwang, Jong San Chang, Xiaoping Wang, Mads Ry Jørgensen, Yu Sheng Chen, Hong Cai Zhou

Research output: Contribution to journal › Article › peer-review

66 Scopus citations

Abstract

A new porous metal - organic framework, PCN-20 with a twisted boracite net topology, was constructed based on a highly conjugated planar tricarboxylate ligand; PCN-20 possesses a large Langmuir surface area of over 4200 m ²/g as well as demonstrates a high hydrogen uptake capacity of 6.2 wt % at 77 K and 50 bar.

Original language	English
Pages (from-to)	7519-7521
Number of pages	3
Journal	Inorganic Chemistry
Volume	48
Issue number	16
DOIs	https://doi.org/10.1021/ic901073w
State	Published - Aug 17 2009
Externally published	Yes

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10.1021/ic901073w

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title = "A large-surface-area boracite-network-topology porous MOF constructed from a conjugated ligand exhibiting a high hydrogen uptake capacity",

abstract = "A new porous metal - organic framework, PCN-20 with a twisted boracite net topology, was constructed based on a highly conjugated planar tricarboxylate ligand; PCN-20 possesses a large Langmuir surface area of over 4200 m 2/g as well as demonstrates a high hydrogen uptake capacity of 6.2 wt % at 77 K and 50 bar.",

author = "Wang, {Xi Sen} and Shengqian Ma and Daqiang Yuan and Yoon, {Ji Woong} and Hwang, {Young Kyu} and Chang, {Jong San} and Xiaoping Wang and J{\o}rgensen, {Mads Ry} and Chen, {Yu Sheng} and Zhou, {Hong Cai}",

year = "2009",

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doi = "10.1021/ic901073w",

language = "English",

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pages = "7519--7521",

journal = "Inorganic Chemistry",

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T1 - A large-surface-area boracite-network-topology porous MOF constructed from a conjugated ligand exhibiting a high hydrogen uptake capacity

AU - Wang, Xi Sen

AU - Ma, Shengqian

AU - Yuan, Daqiang

AU - Yoon, Ji Woong

AU - Hwang, Young Kyu

AU - Chang, Jong San

AU - Wang, Xiaoping

AU - Jørgensen, Mads Ry

AU - Chen, Yu Sheng

AU - Zhou, Hong Cai

PY - 2009/8/17

Y1 - 2009/8/17

N2 - A new porous metal - organic framework, PCN-20 with a twisted boracite net topology, was constructed based on a highly conjugated planar tricarboxylate ligand; PCN-20 possesses a large Langmuir surface area of over 4200 m 2/g as well as demonstrates a high hydrogen uptake capacity of 6.2 wt % at 77 K and 50 bar.

AB - A new porous metal - organic framework, PCN-20 with a twisted boracite net topology, was constructed based on a highly conjugated planar tricarboxylate ligand; PCN-20 possesses a large Langmuir surface area of over 4200 m 2/g as well as demonstrates a high hydrogen uptake capacity of 6.2 wt % at 77 K and 50 bar.

UR - http://www.scopus.com/inward/record.url?scp=68949158209&partnerID=8YFLogxK

U2 - 10.1021/ic901073w

DO - 10.1021/ic901073w

M3 - Article

AN - SCOPUS:68949158209

SN - 0020-1669

VL - 48

SP - 7519

EP - 7521

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 16

ER -

A large-surface-area boracite-network-topology porous MOF constructed from a conjugated ligand exhibiting a high hydrogen uptake capacity

Abstract

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