A hardwon dirhodium paddlewheel with guanidinate type (hpp) bridging ligands

John F. Berry; F. Albert Cotton; Penglin Huang; Carlos A. Murillo; Xiaoping Wang

doi:10.1039/b513406d

A hardwon dirhodium paddlewheel with guanidinate type (hpp) bridging ligands

John F. Berry, F. Albert Cotton, Penglin Huang, Carlos A. Murillo, Xiaoping Wang

Research output: Contribution to journal › Article › peer-review

28 Scopus citations

Abstract

A dirhodium paddlewheel compound which has a Rh₂⁵⁺ core enveloped by four guaninate ligands was prepared. The ligand itself was incorporated into paddlewheel compounds of eleven different metal atoms. Considering the instability the tetraacetate precursor, compound 1 is remarkably stable in crystalline form and remains unchanges after exposure to air for several days. In THF solution the brownish color changes rapidly to purple because of axial coordination by solvent molecules.

Original language	English
Pages (from-to)	3713-3715
Number of pages	3
Journal	Dalton Transactions
Issue number	23
DOIs	https://doi.org/10.1039/b513406d
State	Published - Dec 7 2005
Externally published	Yes

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title = "A hardwon dirhodium paddlewheel with guanidinate type (hpp) bridging ligands",

abstract = "A dirhodium paddlewheel compound which has a Rh25+ core enveloped by four guaninate ligands was prepared. The ligand itself was incorporated into paddlewheel compounds of eleven different metal atoms. Considering the instability the tetraacetate precursor, compound 1 is remarkably stable in crystalline form and remains unchanges after exposure to air for several days. In THF solution the brownish color changes rapidly to purple because of axial coordination by solvent molecules.",

author = "Berry, \{John F.\} and Cotton, \{F. Albert\} and Penglin Huang and Murillo, \{Carlos A.\} and Xiaoping Wang",

year = "2005",

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doi = "10.1039/b513406d",

language = "English",

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journal = "Dalton Transactions",

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T1 - A hardwon dirhodium paddlewheel with guanidinate type (hpp) bridging ligands

AU - Berry, John F.

AU - Cotton, F. Albert

AU - Huang, Penglin

AU - Murillo, Carlos A.

AU - Wang, Xiaoping

PY - 2005/12/7

Y1 - 2005/12/7

N2 - A dirhodium paddlewheel compound which has a Rh25+ core enveloped by four guaninate ligands was prepared. The ligand itself was incorporated into paddlewheel compounds of eleven different metal atoms. Considering the instability the tetraacetate precursor, compound 1 is remarkably stable in crystalline form and remains unchanges after exposure to air for several days. In THF solution the brownish color changes rapidly to purple because of axial coordination by solvent molecules.

AB - A dirhodium paddlewheel compound which has a Rh25+ core enveloped by four guaninate ligands was prepared. The ligand itself was incorporated into paddlewheel compounds of eleven different metal atoms. Considering the instability the tetraacetate precursor, compound 1 is remarkably stable in crystalline form and remains unchanges after exposure to air for several days. In THF solution the brownish color changes rapidly to purple because of axial coordination by solvent molecules.

UR - https://www.scopus.com/pages/publications/29144476474

U2 - 10.1039/b513406d

DO - 10.1039/b513406d

M3 - Article

AN - SCOPUS:29144476474

SN - 1477-9226

SP - 3713

EP - 3715

JO - Dalton Transactions

JF - Dalton Transactions

IS - 23

ER -

A hardwon dirhodium paddlewheel with guanidinate type (hpp) bridging ligands

Abstract

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