A facile synthesis and X-ray structure determination of the first triptycenocrown ethers

Andrei A. Gakh; Richard A. Sachleben; Jeffrey C. Bryan; Bruce A. Moyer

doi:10.1016/0040-4039(95)01760-F

A facile synthesis and X-ray structure determination of the first triptycenocrown ethers

Andrei A. Gakh, Richard A. Sachleben, Jeffrey C. Bryan, Bruce A. Moyer

Chemical Separations Group

Research output: Contribution to journal › Article › peer-review

17 Scopus citations

Abstract

The synthesis of the first triptycenocrown ethers was achieved by two-step procedure which includes condensation of 9,10-bis(chloromethyl)anthracene with polyethylene glycols to yield the intermediate 9,10-anthracenocrown ethers, and subsequent cycloaddition of benzyne leading to the title compound. The structure of 9,10-triptyceno-25-crown-7 (1) and its thallium nitrate complex (Tl-1) were determined by X-Ray diffraction analysis and NMR spectroscopy.

Original language	English
Pages (from-to)	8163-8166
Number of pages	4
Journal	Tetrahedron Letters
Volume	36
Issue number	45
DOIs	https://doi.org/10.1016/0040-4039(95)01760-F
State	Published - 1995

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abstract = "The synthesis of the first triptycenocrown ethers was achieved by two-step procedure which includes condensation of 9,10-bis(chloromethyl)anthracene with polyethylene glycols to yield the intermediate 9,10-anthracenocrown ethers, and subsequent cycloaddition of benzyne leading to the title compound. The structure of 9,10-triptyceno-25-crown-7 (1) and its thallium nitrate complex (Tl-1) were determined by X-Ray diffraction analysis and NMR spectroscopy.",

author = "Gakh, {Andrei A.} and Sachleben, {Richard A.} and Bryan, {Jeffrey C.} and Moyer, {Bruce A.}",

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T1 - A facile synthesis and X-ray structure determination of the first triptycenocrown ethers

AU - Gakh, Andrei A.

AU - Sachleben, Richard A.

AU - Bryan, Jeffrey C.

AU - Moyer, Bruce A.

PY - 1995

Y1 - 1995

N2 - The synthesis of the first triptycenocrown ethers was achieved by two-step procedure which includes condensation of 9,10-bis(chloromethyl)anthracene with polyethylene glycols to yield the intermediate 9,10-anthracenocrown ethers, and subsequent cycloaddition of benzyne leading to the title compound. The structure of 9,10-triptyceno-25-crown-7 (1) and its thallium nitrate complex (Tl-1) were determined by X-Ray diffraction analysis and NMR spectroscopy.

AB - The synthesis of the first triptycenocrown ethers was achieved by two-step procedure which includes condensation of 9,10-bis(chloromethyl)anthracene with polyethylene glycols to yield the intermediate 9,10-anthracenocrown ethers, and subsequent cycloaddition of benzyne leading to the title compound. The structure of 9,10-triptyceno-25-crown-7 (1) and its thallium nitrate complex (Tl-1) were determined by X-Ray diffraction analysis and NMR spectroscopy.

UR - http://www.scopus.com/inward/record.url?scp=0028856267&partnerID=8YFLogxK

U2 - 10.1016/0040-4039(95)01760-F

DO - 10.1016/0040-4039(95)01760-F

M3 - Article

AN - SCOPUS:0028856267

SN - 0040-4039

VL - 36

SP - 8163

EP - 8166

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 45

ER -

A facile synthesis and X-ray structure determination of the first triptycenocrown ethers

Abstract

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