A coordinatively saturated sulfate encapsulated in a metal-organic framework functionalized with urea hydrogen-bonding groups

Radu Custelcean; Bruce A. Moyer; Benjamin P. Hay

doi:10.1039/b511809c

A coordinatively saturated sulfate encapsulated in a metal-organic framework functionalized with urea hydrogen-bonding groups

Radu Custelcean
, Bruce A. Moyer
, Benjamin P. Hay

Chemical Separations Group

Research output: Contribution to journal › Article › peer-review

168 Scopus citations

Abstract

A functional coordination polymer decorated with urea hydrogen-bonding donor groups has been designed for optimal binding of sulfate; self-assembly of a tripodal tris-urea linker with Ag₂SO₄ resulted in the formation of a ID metal-organic framework that encapsulates SO₄ ² anions via twelve complementary hydrogen bonds, which represents the highest coordination number observed for sulfate in a natural or synthetic host.

Original language	English
Pages (from-to)	5971-5973
Number of pages	3
Journal	Chemical Communications
Issue number	48
DOIs	https://doi.org/10.1039/b511809c
State	Published - Dec 28 2005

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title = "A coordinatively saturated sulfate encapsulated in a metal-organic framework functionalized with urea hydrogen-bonding groups",

abstract = "A functional coordination polymer decorated with urea hydrogen-bonding donor groups has been designed for optimal binding of sulfate; self-assembly of a tripodal tris-urea linker with Ag2SO4 resulted in the formation of a ID metal-organic framework that encapsulates SO4 2 anions via twelve complementary hydrogen bonds, which represents the highest coordination number observed for sulfate in a natural or synthetic host.",

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AU - Custelcean, Radu

AU - Moyer, Bruce A.

AU - Hay, Benjamin P.

PY - 2005/12/28

Y1 - 2005/12/28

N2 - A functional coordination polymer decorated with urea hydrogen-bonding donor groups has been designed for optimal binding of sulfate; self-assembly of a tripodal tris-urea linker with Ag2SO4 resulted in the formation of a ID metal-organic framework that encapsulates SO4 2 anions via twelve complementary hydrogen bonds, which represents the highest coordination number observed for sulfate in a natural or synthetic host.

AB - A functional coordination polymer decorated with urea hydrogen-bonding donor groups has been designed for optimal binding of sulfate; self-assembly of a tripodal tris-urea linker with Ag2SO4 resulted in the formation of a ID metal-organic framework that encapsulates SO4 2 anions via twelve complementary hydrogen bonds, which represents the highest coordination number observed for sulfate in a natural or synthetic host.

UR - https://www.scopus.com/pages/publications/29744436667

U2 - 10.1039/b511809c

DO - 10.1039/b511809c

M3 - Article

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SN - 1359-7345

SP - 5971

EP - 5973

JO - Chemical Communications

JF - Chemical Communications

IS - 48

ER -

A coordinatively saturated sulfate encapsulated in a metal-organic framework functionalized with urea hydrogen-bonding groups

Abstract

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