Abstract
A functional coordination polymer decorated with urea hydrogen-bonding donor groups has been designed for optimal binding of sulfate; self-assembly of a tripodal tris-urea linker with Ag2SO4 resulted in the formation of a ID metal-organic framework that encapsulates SO4 2 anions via twelve complementary hydrogen bonds, which represents the highest coordination number observed for sulfate in a natural or synthetic host.
Original language | English |
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Pages (from-to) | 5971-5973 |
Number of pages | 3 |
Journal | Chemical Communications |
Issue number | 48 |
DOIs | |
State | Published - Dec 28 2005 |