A concise approach to the synthesis of opp-dibenzoporphyrins through the heck reaction

  • Rohit Deshpande
  • , Lin Jiang
  • , Gregory Schmidt
  • , John Rakovan
  • , Xiaoping Wang
  • , Kraig Wheeler
  • , Hong Wang

    Research output: Contribution to journalArticlepeer-review

    70 Scopus citations

    Abstract

    A concise approach to the synthesis of functionalized opp-dibenzoporphyrins is described. In this method, introduction of alkenyl groups to the porphyrin periphery through the vicinal 2-fold Heck reaction, 6-φ electrocyclization, and subsequent aromatizaron occur in one pot.

    Original languageEnglish
    Pages (from-to)4251-4253
    Number of pages3
    JournalOrganic Letters
    Volume11
    Issue number19
    DOIs
    StatePublished - Oct 1 2009

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