A concise approach to the synthesis of opp-dibenzoporphyrins through the heck reaction

Rohit Deshpande; Lin Jiang; Gregory Schmidt; John Rakovan; Xiaoping Wang; Kraig Wheeler; Hong Wang

doi:10.1021/ol901615f

A concise approach to the synthesis of opp-dibenzoporphyrins through the heck reaction

Rohit Deshpande, Lin Jiang, Gregory Schmidt, John Rakovan, Xiaoping Wang, Kraig Wheeler, Hong Wang

Single Crystal Diffraction

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Abstract

A concise approach to the synthesis of functionalized opp-dibenzoporphyrins is described. In this method, introduction of alkenyl groups to the porphyrin periphery through the vicinal 2-fold Heck reaction, 6-φ electrocyclization, and subsequent aromatizaron occur in one pot.

Original language	English
Pages (from-to)	4251-4253
Number of pages	3
Journal	Organic Letters
Volume	11
Issue number	19
DOIs	https://doi.org/10.1021/ol901615f
State	Published - Oct 1 2009

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10.1021/ol901615f

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title = "A concise approach to the synthesis of opp-dibenzoporphyrins through the heck reaction",

abstract = "A concise approach to the synthesis of functionalized opp-dibenzoporphyrins is described. In this method, introduction of alkenyl groups to the porphyrin periphery through the vicinal 2-fold Heck reaction, 6-φ electrocyclization, and subsequent aromatizaron occur in one pot.",

author = "Rohit Deshpande and Lin Jiang and Gregory Schmidt and John Rakovan and Xiaoping Wang and Kraig Wheeler and Hong Wang",

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AU - Deshpande, Rohit

AU - Jiang, Lin

AU - Schmidt, Gregory

AU - Rakovan, John

AU - Wang, Xiaoping

AU - Wheeler, Kraig

AU - Wang, Hong

PY - 2009/10/1

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N2 - A concise approach to the synthesis of functionalized opp-dibenzoporphyrins is described. In this method, introduction of alkenyl groups to the porphyrin periphery through the vicinal 2-fold Heck reaction, 6-φ electrocyclization, and subsequent aromatizaron occur in one pot.

AB - A concise approach to the synthesis of functionalized opp-dibenzoporphyrins is described. In this method, introduction of alkenyl groups to the porphyrin periphery through the vicinal 2-fold Heck reaction, 6-φ electrocyclization, and subsequent aromatizaron occur in one pot.

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JO - Organic Letters

JF - Organic Letters

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ER -

A concise approach to the synthesis of opp-dibenzoporphyrins through the heck reaction

Abstract

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