A chain of five chromium(II) atoms: A desired compound with an undesired, unsurprising, but important structure

F. Albert Cotton; Lee M. Daniels; Tongbu Lu; Carlos A. Murillo; Xiaoping Wang

A chain of five chromium(II) atoms: A desired compound with an undesired, unsurprising, but important structure

F. Albert Cotton
, Lee M. Daniels
, Tongbu Lu
, Carlos A. Murillo
, Xiaoping Wang

Research output: Contribution to journal › Article › peer-review

4 Scopus citations

Abstract

Reaction of the dilithium salt of tripyridyldiamine, Li₂tpda, and CrCl₂ in THF gave the pentachromium compound Cr₅(tpda)₄Cl₂·CH₂Cl ₂ in which the metal atoms were arranged in a linear fashion with localized quadruple bonds Cr Cr⋯Cr Cr⋯Cr.

Original language	English
Pages (from-to)	517-518
Number of pages	2
Journal	Journal of the Chemical Society - Dalton Transactions
Issue number	4
State	Published - 1999
Externally published	Yes

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@article{f3d5ed21585b4b8ea192bd04eb5bd4a0,

title = "A chain of five chromium(II) atoms: A desired compound with an undesired, unsurprising, but important structure",

abstract = "Reaction of the dilithium salt of tripyridyldiamine, Li2tpda, and CrCl2 in THF gave the pentachromium compound Cr5(tpda)4Cl2·CH2Cl 2 in which the metal atoms were arranged in a linear fashion with localized quadruple bonds Cr Cr⋯Cr Cr⋯Cr.",

author = "\{Albert Cotton\}, F. and Daniels, \{Lee M.\} and Tongbu Lu and Murillo, \{Carlos A.\} and Xiaoping Wang",

year = "1999",

language = "English",

pages = "517--518",

journal = "Journal of the Chemical Society - Dalton Transactions",

issn = "0300-9246",

publisher = "Royal Society of Chemistry",

number = "4",

}

TY - JOUR

T1 - A chain of five chromium(II) atoms

T2 - A desired compound with an undesired, unsurprising, but important structure

AU - Albert Cotton, F.

AU - Daniels, Lee M.

AU - Lu, Tongbu

AU - Murillo, Carlos A.

AU - Wang, Xiaoping

PY - 1999

Y1 - 1999

N2 - Reaction of the dilithium salt of tripyridyldiamine, Li2tpda, and CrCl2 in THF gave the pentachromium compound Cr5(tpda)4Cl2·CH2Cl 2 in which the metal atoms were arranged in a linear fashion with localized quadruple bonds Cr Cr⋯Cr Cr⋯Cr.

AB - Reaction of the dilithium salt of tripyridyldiamine, Li2tpda, and CrCl2 in THF gave the pentachromium compound Cr5(tpda)4Cl2·CH2Cl 2 in which the metal atoms were arranged in a linear fashion with localized quadruple bonds Cr Cr⋯Cr Cr⋯Cr.

UR - https://www.scopus.com/pages/publications/33751282488

M3 - Article

AN - SCOPUS:33751282488

SN - 0300-9246

SP - 517

EP - 518

JO - Journal of the Chemical Society - Dalton Transactions

JF - Journal of the Chemical Society - Dalton Transactions

IS - 4

ER -

A chain of five chromium(II) atoms: A desired compound with an undesired, unsurprising, but important structure

Abstract

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