TY - JOUR
T1 - 2,9-Bis(5-sulfanylidene-4,5-dihydro-1,3,4-oxadiazol-2-yl)-1, 10-phenanthroline dimethyl sulfoxide disolvate
AU - Rahman, Md A.
AU - Karim, Mohammad
AU - Arifuzzaman, Md
AU - Siddiquee, Tasneem
AU - Daniels, Lee M.
PY - 2014/3
Y1 - 2014/3
N2 - In the title compound, C16H8N6O 2S2·2C2H6OS, the phenanthroline molecule resides on a twofold axis, and the asymmetric unit also contains a slightly disordered [occupancy ratio for S atom of 0.95 (3):0.047 (3)] molecule of dimethyl sulfoxide. The O atoms of the solvent molecule accept hydrogen bonds from the N - H groups of the five-membered 2,3-dihydro-1,3,4-oxadiazole-2-thione ring. This ring is nearly coplanar with the phenanthroline ring, with a dihedral angle between their least-squares planes of 8.86 (6)°. In the crystal, the molecules are linked by C - H⋯O interactions.
AB - In the title compound, C16H8N6O 2S2·2C2H6OS, the phenanthroline molecule resides on a twofold axis, and the asymmetric unit also contains a slightly disordered [occupancy ratio for S atom of 0.95 (3):0.047 (3)] molecule of dimethyl sulfoxide. The O atoms of the solvent molecule accept hydrogen bonds from the N - H groups of the five-membered 2,3-dihydro-1,3,4-oxadiazole-2-thione ring. This ring is nearly coplanar with the phenanthroline ring, with a dihedral angle between their least-squares planes of 8.86 (6)°. In the crystal, the molecules are linked by C - H⋯O interactions.
KW - Data-toparameter ratio = 16.7
KW - Disorder in solvent or counterion
KW - Mean σ(C-C) = 0.005 Å
KW - R factor = 0.067
KW - Single-crystal X-ray study
KW - T = 277 K
KW - wR factor = 0.171
UR - http://www.scopus.com/inward/record.url?scp=84897741847&partnerID=8YFLogxK
U2 - 10.1107/S1600536814003304
DO - 10.1107/S1600536814003304
M3 - Article
AN - SCOPUS:84897741847
SN - 1600-5368
VL - 70
SP - o321-o322
JO - Acta Crystallographica Section E: Structure Reports Online
JF - Acta Crystallographica Section E: Structure Reports Online
IS - 3
ER -