1,3-Bis(pyridineylidene)isoindoline: An isoindoline chelate with a stretched electronic structure

Sanjay Gaire; Briana R. Schrage; Victor N. Nemykin; Christopher J. Ziegler

doi:10.1039/d0dt04347h

1,3-Bis(pyridineylidene)isoindoline: An isoindoline chelate with a stretched electronic structure

Sanjay Gaire, Briana R. Schrage, Victor N. Nemykin, Christopher J. Ziegler

Research output: Contribution to journal › Article › peer-review

6 Scopus citations

Abstract

A bridging carbon analog of the well-studied bis(pyridyl)iminoisoindoline (BPI) can be produced via a one step reaction between diiminoisoindoline and pyridine-2-Acetonitrile. The resultant bis(pyridineylidene)isoindoline (BPYI) is structurally analogous to BPI and can readily form metal complexes. However, it exhibits a markedly different electronic structure with intense absorption bands in the visible region of the spectrum.

Original language	English
Pages (from-to)	826-829
Number of pages	4
Journal	Dalton Transactions
Volume	50
Issue number	3
DOIs	https://doi.org/10.1039/d0dt04347h
State	Published - Jan 21 2021
Externally published	Yes

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abstract = "A bridging carbon analog of the well-studied bis(pyridyl)iminoisoindoline (BPI) can be produced via a one step reaction between diiminoisoindoline and pyridine-2-Acetonitrile. The resultant bis(pyridineylidene)isoindoline (BPYI) is structurally analogous to BPI and can readily form metal complexes. However, it exhibits a markedly different electronic structure with intense absorption bands in the visible region of the spectrum.",

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T2 - An isoindoline chelate with a stretched electronic structure

AU - Gaire, Sanjay

AU - Schrage, Briana R.

AU - Nemykin, Victor N.

AU - Ziegler, Christopher J.

N1 - Publisher Copyright: © The Royal Society of Chemistry.

PY - 2021/1/21

Y1 - 2021/1/21

N2 - A bridging carbon analog of the well-studied bis(pyridyl)iminoisoindoline (BPI) can be produced via a one step reaction between diiminoisoindoline and pyridine-2-Acetonitrile. The resultant bis(pyridineylidene)isoindoline (BPYI) is structurally analogous to BPI and can readily form metal complexes. However, it exhibits a markedly different electronic structure with intense absorption bands in the visible region of the spectrum.

AB - A bridging carbon analog of the well-studied bis(pyridyl)iminoisoindoline (BPI) can be produced via a one step reaction between diiminoisoindoline and pyridine-2-Acetonitrile. The resultant bis(pyridineylidene)isoindoline (BPYI) is structurally analogous to BPI and can readily form metal complexes. However, it exhibits a markedly different electronic structure with intense absorption bands in the visible region of the spectrum.

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U2 - 10.1039/d0dt04347h

DO - 10.1039/d0dt04347h

M3 - Article

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JF - Dalton Transactions

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ER -

1,3-Bis(pyridineylidene)isoindoline: An isoindoline chelate with a stretched electronic structure

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